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Process Patrol

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This project was developed by a former Engineer and now a patent agent assistant studding towards LLM degree. Seeing new inventions is very interesting to me. I created this site to outlines my favorite inventions along with inventions that I believe have potential.

Simplifying conductive plate/via isolation

by Russell, Stephen W.; Rotondaro, Antonio L. P.; Plumton, Donald L.; Carter, Duane E.;



BACKGROUND AND SUMMARY OF THE INVENTION

The present invention relates to integrated circuit structures and fabrication methods, especially to the fabrication of DRAM Arrays.

Background: Capacitor-Under-Bitline DRAM

DRAM cells have a capacitor buried under, or stacked over, the transistor associated with it. Where the capacitor is stacked over the transistor, there are two types of cells: the Capacitor Over Bitline (COB) cell and the Capacitor Under Bitline (CUB). FIG. 4 shows an example of a CUB DRAM architecture, with capacitor structures 30, composed of the conductive storage node layer 16, dielectric layer 18, and plate layer 20, rising above the gates 10 of the transistors in the DRAM array. The use of polysilicon to form the conductive plate layer is changing to the use of metals, such as TiN, to avoid depletion layer formation in the capacitor, which in turns lowers cell capacitance. Bitline 22 runs above the capacitors, with the bitline contact 24 descending through the top capacitor electrode (plate) 20 to contact underlying devices or risers, such as the bitline contact plug 12. As the bitline contact is etched through the conductive plate layer of the capacitor, shorting to this plate by the via must be avoided at all costs, or the DRAM will lose functionality due to inadvertent capacitor leak-age/discharge. Current state-of-art technology utilizes the following flow:

a.) Etch via through the capacitor plate;

b.) Ash and post-etch clean (in no particular order);

c.) Wet etch to isotropically remove that portion of the plate which is immediately adjacent to the via, with e.g. H2O2- or HF-containing aqueous solutions;

d.) conformal deposition and etchback of dielectric 26, generally SiN or SiO2, which insulates the via/plate junction (or partial oxidation of the plate layer if it is still polysilicon).

Simplifying Plate/Via Isolation in CUB DRAM

The present application discloses using a dry (plasma) process to accomplish both the post-etch clean and wet etch steps. Previous work has shown that the use of dilute CFx, in O2-rich remote plasmas will isotropically etch TiN from the top of A1 metallizations. Using this process to remove post-etch residue from the via replaces expensive and environmentally-unfriendly solvent cleans, while simultaneously retracting the capacitor plate material from the via sidewalls.

Advantages of the disclosed methods and structures include simplification of the fabrication process, which in turn reduces costs.

BRIEF DESCRIPTION OF THE DRAWINGS

The disclosed inventions will be described with reference to the accompanying drawings, which show important sample embodiments of the invention and which are incorporated in the specification hereof by reference, wherein:

FIGS. 1A-C are flow charts showing key steps in various embodiments of the disclosed process for retracting the plate layer from around a contact.

FIGS. 2A-C shows a cross-section of a partially fabricated integrated circuit structure at various points during one embodiment of the disclosed process.

FIGS. 3A-B shows a cross-section of a partially fabricated integrated circuit structure at various points during an alternate embodiment of the disclosed process.

FIG. 4 shows a cross-section of one type of CUB DRAM array which can be fabricated using the disclosed process.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

The numerous innovative teachings of the present application will be described with particular reference to the presently preferred embodiment. However, it should be understood that this class of embodiments provides only a few examples of the many advantageous uses of the innovative teachings herein. In general, statements made in the specification of the present application do not necessarily delimit any of the various claimed inventions. Moreover, some statements may apply to some inventive features but not to others.

First Embodiment: One Step Contact Etch

FIG. 1A shows a first embodiment of the process, and will now be discussed. Prior to the disclosed process for isolating the via from the plate layer, the DRAM array will be formed. Only a general discussion of this process will be given here, as there are many methods by which this array can be formed.

Isolation structures, such as the STI isolation of FIG. 3 are formed, followed by the formation of the DRAM transistors. A dielectric layer is deposited and bitline and storage node contacts are formed. Capacitors 30 are formed, having plate layer 20, which is an extension of one node of the capacitors (step 101). In this embodiment, the plate layer consists of approximately 100 nm of TiN. The capacitors are surrounded by dielectric layer 32 and overlain by a further dielectric layer 34, both generally an oxide.


2-oxo-1-[[(substituted sulfonyl)amino]carbonyl]azetidines Adjustable chimney cap support
Adjustable paper guide device Adjustable swimsuit
Adsorption means for radionuclides Air conveyor for gas-sampling tubes
Air saving sleeve gun Air seal valve
Alkali-removable label support and label All-purpose mobile scouring machine
Alternating current motor Amino-tetraalkylbenzoylphthalic acids
Aminomethylindans, -benzofuranes and -benzothiophenes Amusement device
Analysis of pipelined networks Animal feed and process
Antibiotic A204I derivatives Antibiotic B-98891
Apparatus for multi-dimensional fiber management Aqueous polyamide dispersion composition
Arrangement relating to high-speed tools Array type laser diode
Article collection and distribution system Aseptic irrigation syringe
Atomizer wheel with steel bushings Attrition resistant metal/oxygen compositions
Automated statistical data collection system Automatic frequency control apparatus
Automatic microfilm retrieval system Back wire ground clamp
Back-up heater Balanced phase data bus transmitter
Bale loader and shredder Bar code reader
Base station transceiver diagnostic equipment BIMOS-type current switch apparatus
Binocular lens systems Binoculars
Biological decontamination system Bird feeder
Blade for centrifugal blasting wheels Boring tool
Bottled water cooler air filter Brake magnet for watt-hour meters
Breathable backing Built-in awning for recreational vehicle
Bullet alarm Buried heterostructure laser modulator
Burnishing apparatus Cab fairing mounting for truck
Calpaines, production and use thereof Car window defroster
Card connector contact element Card-based voice messaging system
Carpets with improved fuzz-resistance Catalysts
Catheter Certain pyridyl-thiazolidin-4-one having anti-ulcer activity
Charging method and charging device Circuit breaker
Closed chemically enhanced treatment system Clutch
Clutches Collapsible bulk container
Collating document printer Collision avoidance detector
Colour photographic silver halide material Combination weigher
Compositions for protein tyrosine phosphatases Condiment dispensing apparatus
Container and lid Container with butterfly valve
Controller for air conditioner Cooling system for a turbo-compressor
Corneal endothelium protective device Creep testing fixture and method
Crossed-element magnetographic print head Crossing gate arm protection assembly
Crystal oscillator circuit using CMOSFETs Cutting blade holder assembly
Cutting drum web deflector Cutting tool
DC cutting circuit Deflection clip
Demodulator for frequency-keyed communication system Dental articulator with removable tray
Deoxidizer package Deposition of magnesium fluoride films
Determination of software functionality Dinghy spar and equipment carrier
Dioximino cephalosporin antibiotics Drawer interlock structure
Drink preserver Drip level irrigation emitter
Driving assist system Edge protector for electrowinning electrode
Efficient fluid dispensing utensil Electrical appliance control system
Electrical connector Electrical connector
Electrical connector apparatus Electro-optic modulator material
Electromagnetic formed contact surface Electromagnetically actuatable fuel injection valve
Electromechanical needle bar engaging device Electronic sunrise-dependent timepiece
Electronically lighted fishing lure Encapsulating moisture-proof coating
Endodontic tool Enhanced indole biosynthesis
Epoxidation catalyst and process Erasable optical data storage medium
Ethanesulfonyl-piperidine derivatives Extraction furnace
Fibre optic X-ray camera Filter inspection apparatus
Filter with integral structural framework Fluid catalytic cracking
Fluid delivery apparatus Flying bag toy
FM/AM broadcast signal converter Focus detection apparatus
Foldable fish net Foldable, portable basketball goal assembly
Fountain solution supply system Freezer drawer support assembly
Frequency division/multiplication with jitter minimization Friction hinge assembly
Fuel injection valve Fuel transfer control apparatus
Fungicidal composition Golf swing aid
Grinding device for medical waste H.F. amplifier
Hair dryer Hair roller
Hand held trotline reel Headset
Heat transport apparatus Heated rollers
Heating system for vehicles Herbicidally active novel substituted 3-trichloromethyl-1,2,4-thiadiazol-5-yl-oxyacetamides
Hexahydrophthalides High solids acrylic-based coatings
High voltage precharging circuit Holding tank vacuum relief
Hot cathode of X-ray tube Hot food stand
Hot-upgrade/hot-add memory Hovercraft with improved maneuverability
Hydraulic drive control system Hydrocarbon sensing apparatus
Illuminated folding foot peg Image reader/editor with operator interaction
Impact modifiers for thermoplastic resins Impact wrench
Implement weight transfer Incubator
Indole derivatives Infrared filter
Injection needle assembly for endoscope Injection press
Ink compositions Instantaneous start up oscillator
Instrument simulator system Insulated food storage housing assembly
Interactive two-way pager systems Irrigation movers
Keyboard with edge vent Kickboard
Kogation reducing ink Laminate-type ceramic electronic component
Latch for card edge socket Leg exerciser
Lens cap Li-exchanged low silica EMT-containing metallosilicates
Light controller with occupancy sensor Light-emitting dendrimers
Limited broadcast system Lithographic apparatus
Locking actuator for a dispenser Loop polymers
Lotioned tissue ply Low dielectric polyimides
Low temperature storage container Low-density coating for gas sensors
Magnetic disk unit Magnetic stirrer for multiple samples
Manually operable die attach apparatus Manufacturing method of semiconductor device
Markerboard Measurement of moisture-stratified sheet material
Mechanical seal member Meter pit
Method for labelling sugars Method for preparation of N-phosphonomethylglycine
Method of connecting circuit boards Method of making hydrofluorocarbons
Method of preparing a phototool Method of reconstituting mica
Methods for applying surgical splints Methods for fabricating stepped etalons
Methods of treating cellular tissue Mobile hospital unit
Modular game call system Motion sensing alarm
Motor truck Motor-vehicle modular dashboard
Mower deck height adjustment mechanism Muffler for internal combustion engine
Multi-beam antenna Multi-gate tandem decurler
Multicolor heat transfer paper Multipole data switch
Multipurpose cable lock Needle for medical use
Nitroglycerine patch Non-refillable pourer fitment
Nozzle tip for agricultural sprayers One trip milling system
Optical beam scanner Optical recording medium
Optical system for endoscopes Ortho-alkylation of phenols
Oxalylamino substituted indoaniline dyes Paint scraper and associated method
Pattern alignment and cutting system Perivascular self-retaining retractor and method
Permanent antistatic resin composition Personal electric field exposure monitor
Photo electric light detection devices Pipe support and pipeline therewith
Plasmid construction by homologous recombination Polyguanidine foams
Polymer blends Polymer electrolyte fuel cell
Polymerase chimeras Polymorphic compounds
Polyolefin molding composition Porous membrane
Power conversion apparatus Power generation system
Power steering device Power sweeping tool
Preparation of 7-chloroquinoline-8-carboxylic acids Preparation of aromatic iodine compounds
Preparation of biaryl compounds Pressure transducer calibration
Process control of electrophotographic device Process for enzymatically producing L-carnitine
Process for preparing hydrazines Process for preparing pitch foams
Process for preparing purified interleukin-2 Process for producing 2-hydroxy-4-methylthiobutanoic acid
Process for producing 3,3',5,5'-tetra-t butylbiphenol Process for removing contaminant
Programmable question and answer device Protective collar
Protective underwear Pteridine compounds
Pulsed laser control system Pulsed repeater amplifier
Quick check brake indicator Radiator cap with pressure valve
Recreational vehicle carrier Remote distribution frame
Resynchronizing circuit for TDM system Retractable enclosure for vehicle awning
Reverse phase-controlled dimmer Rotary cutting assembly
Rotary finishing tool Rotary knife cutter
Rotatable fiber optic joint Rotor structure
Safety electrical plug Safety guard apparatus
Scaffold bracket Screw conveyor with intermediate bearing
Seat belt tension sensor Self-balancing device
Semi-synthetic peptide antibiotics Semiconductor device
Semiconductor wafer processing system Sensor component
Sequence control method and apparatus Side curtain air bag module
Single finger-opening resilient cap Slide gate plate
Slide plate patty forming apparatus Slide table unit
Solar heating freeze protection system Solder-on connector for coaxial cable
Sonar system Sound reproducing device
Spark plug for internal-combustion engine Sports racket
Static chair Stomach exercise device
Storm proof roofing material Stroller with improved features
Stud for brake booster Subscriber validation system
Supporting apparatus Surface coated products
Swimwear with floatation members Swivel base structure
Synchronization of measurement values Tagging of antialiased images
Tail gate step Thermal transfer sheet
Thermostatic radiator valve Thickened acid microemulsion composition
Time delay source coding Tire handling apparatus
Tire inspection apparatus and method Tire-pressure regulating system
Tissue debriding apparatus Toilet paper holder and dispenser
Tone generation and modification apparatus Toxic work enclosure
Trailer for balancing vehicle Transparent optical switch
Transport and display carton Travelling-wave loom
Trenching or cutting apparatus Trimetallic hydrocarbon conversion catalyst
Turbine nozzle vane Turbine-driven rotary pump
Turbocharger bearing system Urea derivatives
Urine collection assembly for males V-Triazolyl-[4,5-d]-pyrimidines
Vehicle air conditioner Vehicle generator controller
Vehicle suspension Vertical illuminator for microscope
Vesicular film elements Vinylbenzyl thymine monomers
Virtual ground semiconductor memory device Volatile corrosion inhibiting article
Water clarifying apparatus Wavelength tunable diode laser
Welded non-woven endless belt Welding materials for aluminum-coated steel
Wet/dry utility vacuum cleaner Window covering system
[Driving circuit of display device]


FIG. 2A shows a simplified view of the bitline contact as it descends through the plate layer. Resist PR has been deposited and patterned (step 102). This is followed by the etch (step 103) of the contact 35, which passes through the unpatterned conductive plate layer 25. Immediately after the contact etch, the resist is ashed. A further dry etch (step 104), to etch back or retract the TiN plate layer, is performed with the following parameters:

              Source gas (O.sub.2)             4,000 sccm
              Source gas (C.sub.2 F.sub.6)                 6 sccm
              Pressure                        1.5 Torr
              RF power                        850 W


This etchback accomplishes two purposes: at the same time that it etches back the TiN layer, removing generally 100 nm of TiN to form a void between the TiN and the contact, it removes residue left in the contact when it was formed. FIG. 2B shows the contact at this stage of the process.

After this etch is performed, it is followed by deposition (step 105) of a conformal SiN, which is then non-isotropically etched (step 106) to leave the dielectric 40 only in the void formed by the isotropic etch. Finally, the contact will be filled (step 107) with a conductive layer 50, e.g. polysilicon, giving the structure seen in FIG. 2C.

Alternate Embodiment: Two Step Contact Etch

FIG. 1B shows an alternate embodiment, with a two-step etch of the contact. After formation of the capacitors (step 110) and deposition and patterning of the photo-resist (step 111), the etch of the contact (step 112) stops on the plate 20. The resist is ashed and the dry etch of the previous embodiment is performed (step 113), both etching through and retracting the plate, as well as cleaning the contact. The completion of this step is shown in FIG. 3A. Etch of the contact is then completed (step 114), followed by deposition (step 115) and etchback (step 116) of the conformal dielectric. Finally, the contact is filled (step 117), giving the structure shown in FIG. 3B.

Alternate Embodiment: Second Step of Contact Etch Simultaneous with Conformal Dielectric Etch

In a further alternate embodiment, shown in FIG. 1C, after formation of the capacitors (step 120) and patterning of the resist (step 121), the contact etch again stops on the plate (step 122). The resist is ashed, followed by a dry etch to etch through and retract the plate (123). Instead of immediately continuing the contact etch, conformal dielectric 40 is deposited (step 124) to fill the void created by the retraction step. Finally, the etch of the contact is completed (step 125), which also removes excess portions of dielectric layer 40, followed by filling of the contact (step 126).

Alternate Embodiment: Dry Etch Before Resist Ash

In any of the preceding embodiments, the dry etch with CFx/O2 can be performed prior to the stripping of the resist. Additionally, the etch process may be performed in either the same chamber as the ashing process or in a separate chamber.

Alternate Embodiment: Alternate Plate Materials

In addition to TiN, other conductive materials (e.g., WN, TiAlN, TiSiN, or WSiN) can be used to form the plate layer so long as the process is optimized to achieve desired amount of plate retraction.

Alternate Embodiment: Composite Structure for Plate

In an alternate embodiment, a composite structure is used for the plate, e.g. a titanium/TiN structure. The layers must have similar etch rates to prevent partial retraction.

Alternate Embodiment: Alternate Etch Chemistries

In an alternative embodiment, O2/SF6 is used as the etch chemistry for plate retraction. Other process parameters remain the same.

According to a disclosed class of innovative embodiments, there is provided: A fabrication method, comprising the steps of: (a.) etching an opening into a layer of dielectric containing a conductive structure; (b.) performing a dry etch which isotropically removes portions of said conductive structure which are adjacent said opening.

According to another disclosed class of innovative embodiments, there is provided: A fabrication method, comprising the steps of: (a.) forming an array of capacitors and covering said array of capacitors with a first dielectric; (b.) forming an opening through said first dielectric and through a portion of one of said capacitors, to contact a conductive structure underlying said one of said capacitors; (c.) performing a dry etch which isotropically etches portions of said one of said capacitors to produce a void adjacent to said opening.

Modifications and Variations

As will be recognized by those skilled in the art, the innovative concepts described in the present application can be modified and varied over a tremendous range of applications, and accordingly the scope of patented subject matter is not limited by any of the specific exemplary teachings given, but is only defined by the issued claims.

For example, the disclosed method is not only applicable to the pit- or cup-type DRAM cells as shown in FIG. 3, but are also applicable to crown cells or other cell structures which use the capacitor-under-bitline structure.